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![]() Three of these stationary phases will be used to chromatographically resolve enantiomers, as they are composed of liquid polymers of polydimethylsiloxane (PDMS) to which chiral valine or cyclodextrin units are attached. The GC unit of COSAC is equipped with eight capillary columns that will each provide a specific stationary phase for molecular separation. The Cometary Sampling and Composition experiment (COSAC) onboard the Rosetta mission’s lander “Philae” has been designed for the cometary in situ detection and quantification of organic molecules using gas chromatography coupled to mass spectrometry (GC–MS). The European Space Agency’s Rosetta mission was launched in March 2004 in order to reach comet 67P/Churyumov–Gerasimenko by August 2014. In this context, the spectroscopic data generated in this work can provide valuable assistance toward the astrophysical detection of chiral molecules in outer space. The stereoinversion pathways proposed in this work may proceed via photoirradiation in the ISM, which though can be revealed by exploring the excited-state potential energy surface. The feasibility of the pathways under conditions akin to interstellar medium (ISM) is further discussed in terms of natural bond orbital analysis. A few of the probable stereoinversion pathways proposed proceed through the proton or hydrogen atom transfer. Notably, the TS structures traced along the stereochemical pathways resemble the achiral ammonium ylide and imine intermediates as observed in the Strecker synthesis of chiral amino acids. The species including the transition states (TSs) traced along the stereoinversion pathways are characterized using rotational and vibrational computational spectroscopic analysis while accounting for the vibrational corrections to rotational constants and anharmonic effects. ![]() Noncatalytic reaction pathways for the gas-phase stereoinversion in aspartic acid are mapped employing a global reaction route mapping strategy using quantum mechanical computations. ![]() The HIGH of AMC SP might be higher than $62,208 due to other variables (FOMO, Gamma Squeeze, more than 26B synthetic shares, etc). ![]() There are probably many paper hands that will jump in once we short squeeze starts. I believe there will be FOMO when AMC SP starts to run from $100. We will find out the numbers of synthetic shares when Chad & Wes count them. If 26B synthetic shares are covered, AMC SP should be about $62,208. If 9B synthetic shares are covered, AMC SP should be about $21,600.ħ). If 3B synthetic shares are returned (buy back/covered), AMC SP should be about $7,200.Ħ). I will provide my calculations for AMC SP based on my 3B synthetic shares created, 9B and 26B synthetic shares.ĥ). Wes Christian thinks 9B to 26B synthetic shares. I estimated there are about 3B synthetic shares (My estimate is low). If all 100M (legal) shares on loan are returned, AMC SP should be about $158.30. If 90M (legal) shares on loan are returned, AMC SP should be about $146.Ĥ). If 60M (legal) shares on loan are returned, AMC SP should be about $109.ģ). AMC share price jumped from $35 to $72 with 30M (legal) shares returned on June 2nd.Ģ). My calculations for the (legal) shares on loan when returned (first). I did some calculations to come up with the realistic AMC SP when all the (legal) shares are returned. Hey Apes.There are about 100M (legal) shares on loan. He has been providing great info and regularly shares his research to help novice investors: ![]() ![]() BuzzBundle na pas encore été évalué par nos utilisateurs. Classic Style Zine Style Gallery Style Top Therapies To Get Rid Of A Pimple Fast 254 0 2013.10.16 13:01:05 254 0 2013.10. BuzzBundle s’exécute sur les systèmes d’exploitation suivants : Windows. Au départ, il a été ajouté à notre base de données sur. La dernière version de BuzzBundle est actuellement inconnue. Keep track of what people say about your competitors in the social media (you can track competitor mentions by their keywords or URLs, too). BuzzBundle est un logiciel de Shareware dans la catégorie Divers développé par BuzzBundle. Post announcements to multiple social profiles at once - either in real time or by using the scheduler.Ĭreate beautiful-looking reports on all your social media activities and campaigns in a matter of seconds.Īdd important conversations to favorites to check on them later. 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Run profiles on social networks, blogs and forums for each persona. Looking for the right Social Media solution for your business buyers like you are primarily concerned about the real total implementation cost (TCO), full list of features, vendor reliability, user reviews, pros and cons. Key FeaturesĬreate separate personas to post under (e.g., your company’s CEO, PR manager, support representative, etc.) and manage them conveniently in one workspace. 1-Social is more expensive to implement (TCO) than BuzzBundle, 1-Social is rated higher (52/100) than BuzzBundle (50/100). ![]() Find niche influencers who can help your promote your product, boost your content marketing efforts and find new quality leads that turn into paying customers. If you need to manage social for several “personas”, like official company rep for PR, your CEO, customer care, yourself and your grandma, you’ll easily handle them all. 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Vaan, Balthier and Fran have innate Steal. Best defensive spell-casting.Īshe, Penelo and Fran all have innate Cure. Excellent damage against the (prominent) Undead type. Provides limited and poor access to Black Magic. Provides status effects through special ammo. Provides good Black Magic through Shades of Black. Uses katanas, mystic armor and Genji gear. Draws from MAG for damage (plus STR if you choose Greatswords through Espers). Provides exclusive access to Arcane Magic. Provides wide assortment of White and Black Magic. Draws from STR for damage but needs MAG for White Magic. Provides curative and protective magic in late game. Weapon damage doesn't scale with stat gains. ![]() Below average speed due to a sole Swiftness license. Provides good physical damage and sturdy defense. Can provide protective White Magic in late game. Uses daggers, ninja swords, shields and light armor. No magic, with the exception of Shades of Black. Uses hammers, axes, shields and heavy armor. Staves boost elemental magic damage.īreaker Draws from STR + SPD for damage.īlack Mage Provides elemental damage through special ammo. Only the first portion of the guide is applicable to TZA, as you can now double up on jobs, but it's a great resource for quick reference.Īrcher It gives Vaan guns 5 and 6 or it gives Fran esuna, cleanse, and shield block 1.This Final Fantasy XII International Zodiac Job System - Jobs Guide was made for the original IZJS release. In my group #2 only Basch can steal so would it be worth it to give Penelo an esper just for that? Shemhazai is also difficult for me. Zalera gives Vaan +435 hp and it gives Penelo steal/poach. My biggest question is who to give Zalera and Shemhazai to. Vaan, Ravager – Shikari/Foebreaker (Zalera, Shemhazai)Īshe, Paladin – Knight/Time Battlemage (Mateus, Adrammalech, Hashmal) It gives Vaan guns 5 and 6 or it gives Fran esuna, cleanse, and shield block 1. So this is what I'm settled on right now. I'd feel obligated to give him Chaos which would give him a wide range of spells and for whatever reason I don't really like the idea of Basch casting magic. I love the idea of Penelo being a ranged caster/archer, but giving monk to Basch feels strange to me. I've also thought about switching Archer and Monk for Penelo and Basch. I also tried to keep the jobs consistent with the characters and story. With this setup everyone has access to 3 swiftness and both groups have access to all the breaks. Penelo, Wizard - Black Mage/Monk (Chaos, Ultima) Vaan, Ravager Shikari/Foebreaker (Zalera, Shemhazai)īalthier, Gun Mage - Machinist/White Mage (Famfrit, Zodiark)įran, Spellsword - Red Battlemage/Bushi (Belias, Cuchulainn, Zeromus, Exodus)Īshe, Paladin Knight/Time Battlemage (Mateus, Adrammalech, Hashmal) I want to know if you all have any suggestions on the team I'm planning on making. 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HOPE supporters showed up in incredible ways ! Although farther than the other kindergartens, she decided to give it a try, and it was then that everything started to change. Finally, she heard about Hope Kindergarten. She tried to register Tasneem for kindergarten, hoping the exposure to other children would help, but she was refused again and again teachers thought that Tasneem would affect the other children and they did not have the resources to deal with her within a classroom. Tasneem’s mother, however, always believed her daughter could overcome the speech obstacle and searched for resources to help support her development. Her family has tried to encourage her and support her to develop her speech and learn to interact with her environment, but with little outside support, they have been limited in their success. At the age her peers were forming sentences and learning how to interact verbally with their surroundings, Tasneem continued to speak only in one-word sentences due to having the speech delay.Īlthough fully aware of her surroundings, she limited her interactions with others, preferring to sit alone and observe rather than to join other children in play. This was the case for Tasneem, a four-year-old girl from a city 80 km north of the Jordan capital Amman called Al-Mafraq governorate. * When unable to express their needs by words, children can become less confident, reduce their interactions with their surroundings, and begin to reject any changes to their environment. By age 3, their vocabulary increases to about 1,000 words, and they speak in three- and four-word sentences. Reem Omar, Intern in the VHI Regional Office in JordanĪ typical 2-year-old can say about 50 words and speak in two- and three-word sentences. ![]() Our favorite is the green curry ladled over brisket or button mushrooms. The fish sauce’s umami and the honey’s sweetness tame the leaves’ medicinal edge.īrisket Smoke Show Curry Boys BBQ, San AntonioĪt this year-old establishment, Andrew Ho and Sean Wen craft a trio of curries and combine them with smoked meats and jasmine rice in bowls fragrant with lemongrass and garlic. It’s a sturdy taco, dripping with juice, that’s made even more decadent by a dip into a spicy and viscous broth.īrothers Don and Theo Nguyen celebrate their Texas and Asian heritage at a monthly pop-up with offerings such as this one, a variation on a traditional Vietnamese dish, in which they season brisket sausage with lemongrass, honey, fish sauce, and grilled lá lôt leaves. Joseph “JQ” Quellar’s pop-up restaurant has popularized yet another variation on the birria taco that features smoked brisket, smoked oxtail, and shredded cheese in a corn tortilla and is crisped on a griddle. It’s an irresistible collision of flavors.īrisket Birria Quesitacos JQ’s Tex-Mex BBQ, Houston On a flattop he sears small cubes of smoked brisket coated with his signature aloha sauce-a fruity vinaigrette infused with soy and ginger-to achieve the Hawaiian equivalent of burnt ends. Shane Sutton, who grew up on Oahu, serves a Hawaiian-style plate lunch featuring his distinctive pulehu (“quick-charred”) brisket. Pulehu Brisket ShaneBoy’s Craft Hawaiian Grindz, Fort Worth Is there anything more entertaining than constructing a Japanese-style hand roll filled with smoky brisket, confit garlic, pickled and fresh vegetables, house-made hot sauce, and a serrano-miso sauce? An accompanying dish that owners Tatsu Aikawa and Takuya Matsumoto call “hippie bone marrow”-a vegetarian offering made with smoked eggplant-only adds to the fun. Smoked Brisket Bento Kemuri Tatsu-ya, Austin It proved so popular that the dish (also available in a vegetarian-friendly cauliflower version) is now an official item-and CM’s top seller. The owner first offered his rendition as an off-menu item when he opened his joint earlier this year. If you’ve ever eaten a Taco Bell Crunchwrap Supreme and thought it’d be better with chopped brisket inside, then you and Cade Mercer think alike. Smoked Brisket Crunchwrap CM Smokehouse, Austin They add it to a bowl of dry noodles and mix it with sweet corn, chopped brisket, onions, and cilantro for a unique and flavorful ramen. They’ve concocted a rust-hued beef broth as the customary dip for their brisket birria tacos, but they’ve also found another use for the elixir. Rene and Joyce Ramirez offer a wide menu that ranges from ribs and smoked sausage to brisket-stuffed habaneros. ![]() If that happens, there will be a whole lot of options for those who are looking to broaden their smoky horizons. Laugh all you want at vegetarian barbecue, but if the price of beef doesn’t drop, the simple pleasure of smoked brisket on butcher paper may soon become a luxury. Pitmasters have also been putting vegetables at the center of the plate, serving “steak” and “wings” made with smoked cauliflower and “pulled pork” consisting of jackfruit pods. Slurping the broth of a brisket ramen and dipping a sausage link into a rich curry have become essential culinary experiences in this increasingly diverse state. In the four years since we published our previous Top 50 list, we’ve enjoyed meals that draw on Japanese, Vietnamese, and Hawaiian traditions, among others. ![]() But the expansion of ’cue culture isn’t just about tacos. 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